Electrochemical impedance spectroscopy was used to study critical chloride concentration of rebar corrosion in concrete under the condition of dry wet cycles. The method for estimating the critical state of rebar corrosion in concrete was discussed, and the effect of time ratio of drying to wetting on critical chloride concentration was analyzed. The results show that the critical corrosion state can be determined by electrochemical impedance spectroscopy. The critical chloride concentration tends to increase with the increase of time ratio of drying to wetting. The critical chloride concentration has a linear relationship with the saturability of concrete after drying, and decreases with the increase of saturability of concrete after drying.