混凝土修复梯度界面构建及其在海洋环境中性能演变
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1.华南理工大学;2.中交基础设施养护集团有限公司;3.华南理工大学 材料科学与工程学院

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Construction of Gradient Interface for Concrete Repair and its Performance Evolution in Marine Environment
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1.South China University of Technology;2.CCCC Infrastructure Maintenance Group Co., Ltd;3.School of Materials Science and Engineering, South China University of Technology

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    摘要:

    针对海洋环境中混凝土修复界面在荷载与干湿循环耦合作用下易发生粘结劣化的问题,提出一种基于低粘度水性环氧树脂(WER)渗透构建梯度界面的水泥基修复砂浆。结果表明,粘度为200 mPa.s的WER可在修复砂浆层-基体界面形成连续梯度分布,其最大渗透深度约为9.4 mm,显著高于高粘度体系。与未掺WER的修复砂浆相比,WER改性体系28 d界面抗折粘结强度提高约77%。在海水干湿循环与压应力耦合作用下,未改性修复体系在应力水平为0.5时经180 d循环其界面粘结强度下降达50%,而WER改性体系降幅控制在30%以内。同时,低粘度WER改性修复砂浆所构建的梯度界面显著降低了镁离子和硫酸根离子的侵入速率,抑制界面区域水化产物的脱钙与劣变,延缓界面性能退化。研究表明,低粘度WER构建的梯度界面可有效提升修补体系的界面粘结性能与海洋环境服役耐久性。

    Abstract:

    Concrete repair interfaces in marine environments are prone to severe bond degradation under the coupled effects of mechanical loading and seawater wet-dry cycling. A cement-based repair mortar was developed which is modified with low-viscosity waterborne epoxy resin (WER) that subsequently penetrates from the mortar into the substrate to construct a gradient repair interface. Experimental results show that WER with a viscosity of 200 mPa·s can form a continuously gradient distribution at the interface between the repair mortar layer and the substrate, with a maximum penetration depth of approximately 9.4 mm, which is significantly greater than that achieved with high-viscosity systems. Compared to unmodified repair mortar, the 28 d interface flexural bond strength of the WER-modified system increases by approximately 77%. Under the combined action of seawater wet-dry cycles and compressive stress, the unmodified repair system exhibits a 50% reduction in interfacial bond strength after 180 d of cycling at a stress level of 0.5, whereas the degradation in the WER-modified system is limited to less than 30%. Moreover, the gradient interface formed by low-viscosity WER-modified repair mortar significantly decreases the ingress rates of magnesium and sulfate ions, inhibits the decalcification and deterioration of hydration products in the interfacial zone, and retards the degradation of interfacial performance. The study demonstrates that the gradient interface constructed with low-viscosity WER effectively enhances both the interfacial bonding properties and the long-term service durability of the repair system in marine environments.

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  • 收稿日期:2026-01-13
  • 最后修改日期:2026-02-26
  • 录用日期:2026-03-19
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